Anais dos Seminários de Redução, Minério de Ferro e Aglomeração


ISSN 2594-357X

Título

AVALIAÇÃO DO IMPACTO DO TEOR DE ENXOFRE DE CARVÕES METALÚRGICOS NOS SEUS VALORES EM USO

IMPACT ASSESSMENT OF SULFUR CONTENT OF METALLURGICAL COALS ON THEIR VALUES IN USE

DOI

10.5151/4444-4444-26153

Downloads

474 Downloads

Resumo

A origem do enxofre no aço está relacionada com a utilização do coque para a produção de ferro-gusa. Para a maioria dos aços são requeridos baixos teores de enxofre porque este elemento afeta a isotropia das propriedades mecânicas, notadamente a tenacidade. Este trabalho tem como objetivo avaliar o impacto do teor de enxofre dos carvões metalúrgicos no seu valor em uso. Valor em uso é o preço máximo que uma determinada empresa está disposta a pagar por um material de substituição, sem deteriorar os resultados econômicos. A dessulfuração de ferrogusa e o impacto do teor de enxofre dos carvões no seu valor em uso foram avaliados considerando utilização de escórias sintéticas. Os resultados mostraram que para 4 das 5 condições avaliadas os valores em uso dos carvões foram maiores que a referência do mercado. Considerando o preço do carvão de referência igual a 120,00 $/t o valor em uso referência do mercado, assumindo 0,10% de enxofre adicional no carvão é de 118,80 $/t. Nas simulações de dessulfuração com escória sintética os valores em uso foram estimados entre 118,55 $/t e 119,34 $/t.

 

The origin of sulfur in steel is mainly related to the use of coke on pig iron production in blast furnaces. For most steels low sulfur levels are required because this element affects the isotropy of mechanical properties, especially toughness. This work aims to assess the impact of the sulfur content of metallurgical coals on their value in use. Value in use is the maximum price that a particular company is willing to pay for a replacement material without deteriorating economic results. The pig iron desulfurization and the impact of sulfur content of coals on its value in use were evaluated considering use of synthetic slags. The results showed that in the 4 of the 5 evaluated conditions values in use of coals were higher than the market reference. Considering the price of the reference coal equal to 120,00 $/t the market reference of value in use assuming additional sulfur of 0,10% in the coal is 118,80 $/t. In the simulations of desulfurization with synthetic slag values in use are estimated between 118,55 $/t and 119,34 $/t.

Palavras-chave

Dessulfuração, Enxofre, Valor em uso, Escória sintética

Desulfurization, Sulfur, Value in use, Synthetic slag

Como citar

Leite, Michel Rodrigues; Castro, Luiz Fernando Andrade de. AVALIAÇÃO DO IMPACTO DO TEOR DE ENXOFRE DE CARVÕES METALÚRGICOS NOS SEUS VALORES EM USO , p. 29-38. In: 45º Ironmaking / 16º Iron Ore / 3º Agglomeration, Rio de Janeiro, 2015.
ISSN: 2594-357X , DOI 10.5151/4444-4444-26153

Whoops, looks like something went wrong.

(1/1) ErrorException

fwrite(): write of 1826 bytes failed with errno=28 No space left on device

in StreamHandler.php line 131
at HandleExceptions->handleError(8, 'fwrite(): write of 1826 bytes failed with errno=28 No space left on device', '/var/www/webroot/ROOT/vendor/monolog/monolog/src/Monolog/Handler/StreamHandler.php', 131, array('stream' => resource, 'record' => array('message' => 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 14:33:52] production.ERROR: file_put_contents(): write of 349 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 349 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'PjUGbL7wI8xiXHq...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} ')))
at fwrite(resource, '[2025-05-30 14:33:52] production.ERROR: file_put_contents(): write of 349 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 349 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'PjUGbL7wI8xiXHq...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} ')in StreamHandler.php line 131
at StreamHandler->streamWrite(resource, array('message' => 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 14:33:52] production.ERROR: file_put_contents(): write of 349 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 349 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'PjUGbL7wI8xiXHq...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in StreamHandler.php line 117
at StreamHandler->write(array('message' => 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 14:33:52] production.ERROR: file_put_contents(): write of 349 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 349 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'PjUGbL7wI8xiXHq...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in AbstractProcessingHandler.php line 39
at AbstractProcessingHandler->handle(array('message' => 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 14:33:52] production.ERROR: file_put_contents(): write of 349 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 349 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'PjUGbL7wI8xiXHq...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in Logger.php line 344
at Logger->addRecord(400, 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Logger.php line 707
at Logger->error('file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Writer.php line 203
at Writer->writeLog('error', 'file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Writer.php line 114
at Writer->error('file_put_contents(): write of 349 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Handler.php line 113
at Handler->report(object(ErrorException))in Handler.php line 100
at Handler->report(object(ErrorException))in HandleExceptions.php line 81
at HandleExceptions->handleException(object(ErrorException))