Anais do Congresso Anual da ABM


ISSN 2594-5327

72nd ABM Annual Congress vol. 72, num.72 (2017)


Título

O ESTUDO DA REMOÇÃO DO CO2+, CU2+ E NI2+ DE UMA SOLUÇÃO AQUOSA PELA RESINA QUELANTE PUROLITE S950 SOB O EFEITO DA VARIAÇÃO DO PH

THE STUDY OF THE REMOVAL OF CO, CU AND NI FROM AQUEOUS SOLUTION BY RESIN CHELATING PUROLITE S950 UNDER THE EFFECT OF PH VARIATION

DOI

10.5151/1516-392X-30241

Downloads

337 Downloads

Resumo

Com a preocupação ambiental, econômica e social perante o descarte de metais oriundos da mineração, busca-se por métodos alternativos e sustentáveis de tratamento e recuperação. Dessa forma, o processo escolhido foi o de troca iônica e o estudo investiga a adsorção do Co2+, Cu2+ e Ni2+ por meio da resina quelante Purolite S950. A resina foi escolhida pela sua capacidade de adsorção dos metais de transição de uma solução ácida. Portanto, o trabalho tem como objetivo investigar o efeito da variação do pH 0,5-2,0, considerando o tempo de contato de 120 min a 25 ºC. Os ensaios foram executados em batelada e as amostras analisadas pela técnica de espectrometria de fluorescência de raios-x de energia dispersiva (EDX). Por meio dos ensaios realizados, foi concluído que a resina quelante Purolite S950 utilizada no estudo foi capaz de remover os metais, destacando a extração de 96,3 % Co2+, 94,8 % Cu2+ e 75,3 % Ni2+, quando a solução estava condicionada em pH 2,0.

 

With environmental, economic and social concern about the disposal of metals from mining, it is sought by alternative and sustainable methods of treatment and recovery. Thus, the chosen process was the ion exchange and the study investigates the adsorption of Co2+, Cu2+ and Ni2+ by means of the chelating resin Purolite S950. The resin was chosen because of its ability to adsorb the transition metals of an acidic solution. Therefore, the objective of this work is to investigate the effect of pH variation 0.5 2.0, for contact time of 120 min at 25°C. The tests were carried out in batch and the samples analyzed by the technique of x-ray fluorescence spectrometry energy dispersive (EDX). It was concluded that chelating resin Purolite S950 used in the study was able to remove the metals. When the solution was conditioned at pH 2.0, 96.3% Co2+, 94.8% Cu2+ and 75.3% Ni2+ were adsorbed.

Palavras-chave

Hidrometalurgia, Troca iônica, Metal de Transição.

Hydrometallurgy, Ion Exchange, Transition metal.

Como citar

Perez, Isadora Dias; Correa, Mónica Maria Jiménez; Tenório, Jorge Alberto Soares; Espinosa, Denise Crocce Romano. O ESTUDO DA REMOÇÃO DO CO2+, CU2+ E NI2+ DE UMA SOLUÇÃO AQUOSA PELA RESINA QUELANTE PUROLITE S950 SOB O EFEITO DA VARIAÇÃO DO PH , p. 441-448. In: 72nd ABM Annual Congress, São Paulo, 2017.
ISSN: 2594-5327 , DOI 10.5151/1516-392X-30241

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(1/1) ErrorException

fwrite(): write of 1826 bytes failed with errno=28 No space left on device

in StreamHandler.php line 131
at HandleExceptions->handleError(8, 'fwrite(): write of 1826 bytes failed with errno=28 No space left on device', '/var/www/webroot/ROOT/vendor/monolog/monolog/src/Monolog/Handler/StreamHandler.php', 131, array('stream' => resource, 'record' => array('message' => 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 09:25:39] production.ERROR: file_put_contents(): write of 386 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 386 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'NddqvHFhMhSKuns...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} ')))
at fwrite(resource, '[2025-05-30 09:25:39] production.ERROR: file_put_contents(): write of 386 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 386 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'NddqvHFhMhSKuns...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} ')in StreamHandler.php line 131
at StreamHandler->streamWrite(resource, array('message' => 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 09:25:39] production.ERROR: file_put_contents(): write of 386 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 386 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'NddqvHFhMhSKuns...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in StreamHandler.php line 117
at StreamHandler->write(array('message' => 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 09:25:39] production.ERROR: file_put_contents(): write of 386 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 386 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'NddqvHFhMhSKuns...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in AbstractProcessingHandler.php line 39
at AbstractProcessingHandler->handle(array('message' => 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', 'context' => array('exception' => object(ErrorException)), 'level' => 400, 'level_name' => 'ERROR', 'channel' => 'production', 'datetime' => object(DateTime), 'extra' => array(), 'formatted' => '[2025-05-30 09:25:39] production.ERROR: file_put_contents(): write of 386 bytes failed with errno=28 No space left on device {"exception":"[object] (ErrorException(code: 0): file_put_contents(): write of 386 bytes failed with errno=28 No space left on device at /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:122)[stacktrace]#0 [internal function]: Illuminate\\\\Foundation\\\\Bootstrap\\\\HandleExceptions->handleError(8, \'file_put_conten...\', \'/var/www/webroo...\', 122, Array)#1 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php(122): file_put_contents(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', 2)#2 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/FileSessionHandler.php(83): Illuminate\\\\Filesystem\\\\Filesystem->put(\'/var/www/webroo...\', \'a:5:{s:6:\\"_toke...\', true)#3 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Store.php(128): Illuminate\\\\Session\\\\FileSessionHandler->write(\'NddqvHFhMhSKuns...\', \'a:5:{s:6:\\"_toke...\')#4 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Session/Middleware/StartSession.php(87): Illuminate\\\\Session\\\\Store->save()#5 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(218): Illuminate\\\\Session\\\\Middleware\\\\StartSession->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#6 /var/www/webroot/ROOT/vendor/laravel/framework/src/Illuminate/Foundation/Http/Kernel.php(189): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminateMiddleware(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#7 /var/www/webroot/ROOT/public/index.php(59): Illuminate\\\\Foundation\\\\Http\\\\Kernel->terminate(Object(Illuminate\\\\Http\\\\Request), Object(Illuminate\\\\Http\\\\Response))#8 {main}"} '))in Logger.php line 344
at Logger->addRecord(400, 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Logger.php line 707
at Logger->error('file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Writer.php line 203
at Writer->writeLog('error', 'file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Writer.php line 114
at Writer->error('file_put_contents(): write of 386 bytes failed with errno=28 No space left on device', array('exception' => object(ErrorException)))in Handler.php line 113
at Handler->report(object(ErrorException))in Handler.php line 100
at Handler->report(object(ErrorException))in HandleExceptions.php line 81
at HandleExceptions->handleException(object(ErrorException))