Título

DEVELOPMENT OF X-80 HTP LINEPIPE STEEL OVER 40 YEARS

DEVELOPMENT OF X-80 HTP LINEPIPE STEEL OVER 40 YEARS

Autoria

John Malcolm Gray

DOI

10.5151/1516-392X-24347

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Resumo

Interest in X-80 linepipe steels emerged in the early 1980’s and it was first used in 1985 by Ruhr Gas [1]. The early steels were extensions of conventional Nb-V or Nb-Mo microalloyed X-70 steels but other alloying concepts emerged based on Nb-Mo-B alloying (NKSTAF [2] and ULCB [3]). The latter had acicular ferrite/bainitic microstructures and carbon contents below 0.05 percent. In parallel renewed interest developed in ultra low carbon (0.02 percent) higher niobium steels which had first been studied in 1962 [4]. Such steels exhibited excellent notch toughness when processed with high finish rolling temperatures (>950°C) which made them suitable for processing on weak, older rolling mills. With time such steels, designated “High Temperature Processed”, or HTP steels, were further optimized and produced in modern, very strong rolling mills due to their superior economy compared with traditional vanadium and molybdenum containing steels. The chronology of the HTP development is presented in the present paper. Full scale demonstration heats of a 0.06 percent carbon 0.10 percent niobium steel were produced by Bofors Steel Plant in 1972 and were converted from slabs to plates by nine different steel mills [5-7]. Commercial application in API Grade X-70 first occurred in Canada in 1974 [8,9] but the concept was only used sporadically after that until 1998 when it was applied for the API Grade X-70 Sour Service Cantarell Project [10] in Mexico. Soon thereafter, the El Paso Cheyenne Plains Project used a 0.05%C 0.095%Nb 0.27%Cr variant of the HTP steel [10-12]. Nowadays the HTP concept is being utilized for construction of approximately 6000 km of 48” OD x 18.4 mm X-80 per year in China. The metallurgical principles and history of the development are presented in details in this paper.

 

Interest in X-80 linepipe steels emerged in the early 1980’s and it was first used in 1985 by Ruhr Gas [1]. The early steels were extensions of conventional Nb-V or Nb-Mo microalloyed X-70 steels but other alloying concepts emerged based on Nb-Mo-B alloying (NKSTAF [2] and ULCB [3]). The latter had acicular ferrite/bainitic microstructures and carbon contents below 0.05 percent. In parallel renewed interest developed in ultra low carbon (0.02 percent) higher niobium steels which had first been studied in 1962 [4]. Such steels exhibited excellent notch toughness when processed with high finish rolling temperatures (>950°C) which made them suitable for processing on weak, older rolling mills. With time such steels, designated “High Temperature Processed”, or HTP steels, were further optimized and produced in modern, very strong rolling mills due to their superior economy compared with traditional vanadium and molybdenum containing steels. The chronology of the HTP development is presented in the present paper. Full scale demonstration heats of a 0.06 percent carbon 0.10 percent niobium steel were produced by Bofors Steel Plant in 1972 and were converted from slabs to plates by nine different steel mills [5-7]. Commercial application in API Grade X-70 first occurred in Canada in 1974 [8,9] but the concept was only used sporadically after that until 1998 when it was applied for the API Grade X-70 Sour Service Cantarell Project [10] in Mexico. Soon thereafter, the El Paso Cheyenne Plains Project used a 0.05%C 0.095%Nb 0.27%Cr variant of the HTP steel [10-12]. Nowadays the HTP concept is being utilized for construction of approximately 6000 km of 48” OD x 18.4 mm X-80 per year in China. The metallurgical principles and history of the development are presented in details in this paper.

Palavras-chave

API X80, Acicular Ferrite/Bainite, Cantarell Project, High Temperature Processing (HTP)

API X80, Acicular Ferrite/Bainite, Cantarell Project, High Temperature Processing (HTP)