Title

NEW VIEW OF THE ASSOCIATED MODEL AND CASE APPLICATIONS

NEW VIEW OF THE ASSOCIATED MODEL AND CASE APPLICATIONS

Authorship

CLAVAGUERAMORA, MARIATERESA; TOURON, JOSÉ LUÍS; RODRIGUEZVIEJO, JAVIER; CLAVAGUERA, NARCÍS

CLAVAGUERAMORA, MARIATERESA

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TOURON, JOSÉ LUÍS

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RODRIGUEZVIEJO, JAVIER

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CLAVAGUERA, NARCÍS

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DOI

10.5151/2594-5327-3036

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Abstract

Compound forming molten alloys, both ionic and covalent, show very often large deviations from ideal liquid solutions. It is shown that the associated solution model may be as useful as other currently used models to reproduce the experimental behavior observed in these molten alloys, and it may provide, even, a simpler view of the nature of the relevant interactions in the liquid solution phase. Experimental thermodynamic data in the rich metal part of metal-oxygen systems, like Cu-O are presented and analyzed with the associated solution model.

Compound forming molten alloys, both ionic and covalent, show very often large deviations from ideal liquid solutions. It is shown that the associated solution model may be as useful as other currently used models to reproduce the experimental behavior observed in these molten alloys, and it may provide, even, a simpler view of the nature of the relevant interactions in the liquid solution phase. Experimental thermodynamic data in the rich metal part of metal-oxygen systems, like Cu-O are presented and analyzed with the associated solution model.

Keywords

Associates, quasi-chemical model

Associates, quasi-chemical model